Abstract
A spectral gap above the closed-shell Fermi sea would, if it persisted in the thermodynamic limit, immediately give the Dirac exchange constant. It does not persist: the one-particle gap at the Fermi surface collapses. This paper develops a thin-shell substitute and uses it to bound the indirect Coulomb energy of arbitrary states. In a finite cell, small kinetic excess above the closed-shell determinant forces overlap with the Fermi sea and closeness of any bounded observable to its Fermi-sea expectation. In the thermodynamic limit, the same mechanism with a thin Fermi shell forces all gapless fluctuations into a shell of $O(\eta L^3)$ orbitals
Conductor
| Mode | Human + AI co-author |
|---|---|
| Conductor (human) | Dong Bai |
| AI co-author | Claude Opus 4.7 |
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